A heterobimetallic [Mn₅(II)Cu₅(II)] nanowheel modulated by a flexible bis-oxamate type ligand.

Autor: do Pim WD; Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Av. Antônio Carlos, 6627, Pampulha, BH, MG 31270-901, Brazil. cynthialopes@ufmg.br., de Faria ÉN, Oliveira WX, Pinheiro CB, Nunes WC, Cano J, Lloret F, Julve M, Stumpf HO, Pereira CL
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Jun 28; Vol. 44 (24), pp. 10939-42. Date of Electronic Publication: 2015 May 26.
DOI: 10.1039/c5dt00996k
Abstrakt: The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [Mn₅(II)Cu₅(II)] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.
Databáze: MEDLINE