| Autor: |
Faizi MS; Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India., Sharkina NO; National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, Ukraine., Davydenko YM; National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, Ukraine. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Jan 21; Vol. 71 (Pt 2), pp. m31-2. Date of Electronic Publication: 2015 Jan 21 (Print Publication: 2015). |
| DOI: |
10.1107/S2056989015000778 |
| Abstrakt: |
In the mononuclear title complex, [CdBr2(C20H17N3)(C3H7NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-yl-methyl-ene)ethan-amine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd-N = 2.401 (3) Å] and one di-methyl-formamide O-atom donor [Cd-O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd-N = 2.293 (3) Å] and two bromides [Cd-Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the Cd(II) atom from the equatorial plane being 0.046 (1) Å. An intra-molecular C-H⋯Br inter-action occurs. In the crystal, N-H⋯Br inter-actions generate [101] chains. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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