Crystal structure of bis-(thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.

Autor: Nawaz S; Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan., Tahir MN; Department of physics, University of Sargodha, Sargodha, Punjab, Pakistan., Nadeem MA; Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan., Mehmood B; Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan., Ahmad S; Department of Chemistry, University of Engineering and Technology, Lahore 54890, Pakistan.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2015 Jan 28; Vol. 71 (Pt 2), pp. 220-2. Date of Electronic Publication: 2015 Jan 28 (Print Publication: 2015).
DOI: 10.1107/S2056989015001395
Abstrakt: In the title salt, [Ag(CH4N2S)2(PPh3)2]NO3, the Ag(I) atom is coordinated by two thio-urea S atoms and two tri-phenyl-phosphane P atoms in a distorted tetra-hedral geometry, with bond angles in the range 102.90 (4)-123.29 (4)°. The Ag-S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C-H⋯O, C-H⋯S, N-H⋯O and N-H⋯S hydrogen bonds, generating (10-1) sheets.
Databáze: MEDLINE