Ruthenium-catalyzed aerobic oxidative decarboxylation of amino acids: a green, zero-waste route to biobased nitriles.

Autor: Claes L; Centre for Surface Chemistry and Catalysis, Department of Microbial and Molecular Systems, KU Leuven - University of Leuven, Kasteelpark Arenberg 23, post box 2461, 3001 Heverlee, Belgium. Dirk.DeVos@biw.kuleuven.be., Verduyckt J, Stassen I, Lagrain B, De Vos DE
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Apr 18; Vol. 51 (30), pp. 6528-31.
DOI: 10.1039/c5cc00181a
Abstrakt: Oxidative decarboxylation of amino acids into nitriles was performed using molecular oxygen as terminal oxidant and a heterogeneous ruthenium hydroxide-based catalyst. A range of amino acids was oxidized in very good yield, using water as the solvent.
Databáze: MEDLINE