| Autor: |
Yao S; Technische Universität Berlin, Department of Chemistry: Metalorganics and Inorganic Materials, Sekr. C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany. matthias.driess@tu-berlin.de., Szilvási T, Lindenmaier N, Xiong Y, Inoue S, Adelhardt M, Sutter J, Meyer K, Driess M |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Apr 11; Vol. 51 (28), pp. 6153-6. |
| DOI: |
10.1039/c5cc00147a |
| Abstrakt: |
The selective transformation of white phosphorus with a β-diketiminato iron(I) toluene complex under mild reaction conditions is reported which furnishes a new dinuclear iron(III) Fe2(P2)2 complex with two bridging P2(2-) ligands. Its reduction with potassium results in the formation of the first delocalised mixed-valent bis-diphosphido iron(II,III) complex which is isostructural with the neutral Fe2P4 precursor. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
