| Autor: |
Ahn ST; School of Engineering, Brown University, Providence, RI, USA. tayhas_palmore@brown.edu., Bielinski EA, Lane EM, Chen Y, Bernskoetter WH, Hazari N, Palmore GT |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Apr 07; Vol. 51 (27), pp. 5947-50. Date of Electronic Publication: 2015 Mar 04. |
| DOI: |
10.1039/c5cc00458f |
| Abstrakt: |
An iridium(III) trihydride complex supported by a pincer ligand with a hydrogen bond donor in the secondary coordination sphere promotes the electrocatalytic reduction of CO2 to formate in water/acetonitrile with excellent Faradaic efficiency and low overpotential. Preliminary mechanistic experiments indicate formate formation is facile while product release is a kinetically difficult step. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
