Photoinduced guest transformation promotes translocation of guest from hydroxypropyl-β-cyclodextrin to cucurbit[7]uril.

Autor: Fedorov YV; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., 119991 Moscow, Russian Federation. fedorova@ineos.ac.ru., Tkachenko SV, Chernikova EY, Godovikov IA, Fedorova OA, Isaacs L
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2015 Jan 25; Vol. 51 (7), pp. 1349-52.
DOI: 10.1039/c4cc08474h
Abstrakt: We report that three-component systems comprising styryl dyes (1 or 2) and two hosts (hydroxypropyl-β-cyclodextrin (HP-β-CD) and cucurbit[7]uril (CB[7])) undergo photoinduced transformation and translocation of the styryl guest from the cavity of HP-β-CD to CB[7]. We find that the protonation of guest trans-1 or the addition of Ba(2+) as competitor for CB[7] triggers dissociation of the container-guest complexes.
Databáze: MEDLINE