| Autor: |
Takaluoma EM; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland., Oilunkaniemi R; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland., Lehmann CW; Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim an der Ruhr, Germany., Laitinen RS; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2014 Oct 31; Vol. 70 (Pt 11), pp. m389. Date of Electronic Publication: 2014 Oct 31 (Print Publication: 2014). |
| DOI: |
10.1107/S1600536814023733 |
| Abstrakt: |
In the title compound, [Tm(C6H5Se)3(C4H8O)3], the Tm(III) atom lies on a threefold rotation axis and is coordinated by three phenyl-seleno-late ligands and three tetra-hydro-furan ligands leading to a distorted fac-octa-hedral coordination environment. The Tm-Se and Tm-O bond lengths are 2.7692 (17) and 2.345 (10) Å, respectively, and the bond angles are 91.32 (6)° for Se-Tm-Se, 92.6 (2) and 94.4 (2)° for Se-Tm-O, and 81.2 (3)° for O-Tm-O. In the crystal, the discrete complexes are linked by van der Waals inter-actions only. The crystal was refined as a non-merohedral twin (ratio = 0.65:0.35). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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