| Autor: |
Gbabode G; Département de Physique, Faculté des Sciences, and ‡Laboratoire de Chimie des Polymères, Faculté des Sciences, Université libre de Bruxelles (ULB) , Boulevard du Triomphe, 1050 Brussels, Belgium., Dohr M, Niebel C, Balandier JY, Ruzié C, Négrier P, Mondieig D, Geerts YH, Resel R, Sferrazza M |
| Jazyk: |
angličtina |
| Zdroj: |
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2014 Aug 27; Vol. 6 (16), pp. 13413-21. Date of Electronic Publication: 2014 Aug 07. |
| DOI: |
10.1021/am5015315 |
| Abstrakt: |
A detailed structural study of the bulk and thin film phases observed for two potential high-performance organic semiconductors has been carried out. The molecules are based on [1]benzothieno[3,2-b]benzothiophene (BTBT) as conjugated core and octyl side groups, which are anchored either symmetrically at both sides of the BTBT core (C8-BTBT-C8) or nonsymmetrically at one side only (C8-BTBT). Thin films of different thickness (8-85 nm) have been prepared by spin-coating for both systems and analyzed by combining specular and grazing incidence X-ray diffraction. In the case of C8-BTBT-C8, the known crystal structure obtained from single-crystal investigations is observed within all thin films, down to a film thickness of 9 nm. In the case of C8-BTBT, the crystal structure of the bulk phase has been determined from X-ray powder diffraction data with a consistent matching of experimental and calculated X-ray diffraction patterns (Rwp = 5.8%). The packing arrangement of C8-BTBT is similar to that of C8-BTBT-C8, that is, consisting of a lamellar structure with molecules arranged in a "herringbone" fashion, yet with lamellae composed of two head-to-head (or tail-to-tail as the structure is periodic) superimposed molecules instead of only one molecule for C8-BTBT-C8. As for C8-BTBT-C8, we demonstrate that the same phase is observed in bulk and thin films for C8-BTBT whatever the film thickness investigated. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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