| Autor: |
Takaluoma EM; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland., Oilunkaniemi R; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland., Laitinen RS; Department of Chemistry, PO Box 3000, FI-90014 University of Oulu, Finland. |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2014 May 17; Vol. 70 (Pt 6), pp. m215. Date of Electronic Publication: 2014 May 17 (Print Publication: 2014). |
| DOI: |
10.1107/S1600536814010678 |
| Abstrakt: |
The asymmetric unit of the title compound, [PdCl(C9H12NSe)(C18H15P)], contains two independent mol-ecules. In both cases, the Pd(2+) cations are coordinated by the Se and N atoms of the chelating bidentate 2-[(di-methyl-amino)-meth-yl]benzene-seleno-late ligand. The chloride ligand lies trans to selenium and the tri-phenyl-phosphane ligand is trans to nitro-gen. The Pd-Se bond lengths in the two independent coordination environments of Pd are 2.3801 (4) and 2.3852 (4) Å, the Pd-P bond lengths are 2.2562 (8) and 2.2471 (8) Å, the Pd-N bond lengths are 2.172 (2) and 2.158 (2) Å, and the Pd-Cl bond lengths are 2.3816 (8) and 2.3801 (8) Å. The square-planar coordination around one Pd(2+) cation is less distorted than that around the other. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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