| Autor: |
Nelson DJ; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife, KY16 9ST, UK. snolan@st-andrews.ac.uk., Manzini S, Urbina-Blanco CA, Nolan SP |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Sep 18; Vol. 50 (72), pp. 10355-75. |
| DOI: |
10.1039/c4cc02515f |
| Abstrakt: |
While the fundamental series of [2+2]cycloadditions and retro[2+2]cycloadditions that make up the pathways of ruthenium-catalysed metathesis reactions is well-established, the exploration of mechanistic aspects of alkene metathesis continues. In this Feature Article, modern mechanistic studies of the alkene metathesis reaction, catalysed by well-defined ruthenium complexes, are discussed. Broadly, these concern the processes of pre-catalyst initiation, propagation and decomposition, which all have a considerable impact on the overall efficiency of metathesis reactions. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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