| Autor: |
Shiga T; Graduate School of Pure and Applied Sciences, University of Tsukuba , Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan., Tetsuka T, Sakai K, Sekine Y, Nihei M, Newton GN, Oshio H |
| Jazyk: |
angličtina |
| Zdroj: |
Inorganic chemistry [Inorg Chem] 2014 Jun 16; Vol. 53 (12), pp. 5899-901. Date of Electronic Publication: 2014 Jun 03. |
| DOI: |
10.1021/ic500964m |
| Abstrakt: |
A cyanide-bridged decanuclear [Co6Fe4] cluster was synthesized by a one-pot reaction, and the magnetic properties and electronic configuration were investigated. The complex displayed thermally controlled electron-transfer-coupled spin transition (ETCST) behavior between Co(III) low-spin-NC-Fe(II) low-spin and Co(II) high-spin-NC-Fe(III) low-spin states, as confirmed by single-crystal X-ray, magnetic, and Mössbauer analyses. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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