Additional new minor cucurbitane glycosides from Siraitia grosvenorii.

Autor: Prakash I; The Coca-Cola Company, Organic Chemistry Department, Global Research and Development, One Coca-Cola Plaza, Atlanta, GA 30313, USA. iprakash@coca-cola.com., Chaturvedula VS; Natural Ingredient Development, Blue California, 30111 Tomas, Rancho Santa Margarita, CA 92688, USA. saipc@bluecal-ingredients.com.
Jazyk: angličtina
Zdroj: Molecules (Basel, Switzerland) [Molecules] 2014 Mar 24; Vol. 19 (3), pp. 3669-80. Date of Electronic Publication: 2014 Mar 24.
DOI: 10.3390/molecules19033669
Abstrakt: Continuous phytochemical studies of the crude extract of Luo Han Guo (Siraitia grosvenorii) furnished three additional new cucurbitane triterpene glycosides, namely 11-deoxymogroside V, 11-deoxyisomogroside V, and 11-deoxymogroside VI. The structures of all the isolated compounds were characterized on the basis of extensive NMR and mass spectral data as well as hydrolysis studies. The complete ¹H- and ¹³C-NMR spectral assignments of the three unknown compounds are reported for the first time based on COSY, TOCSY, HSQC, and HMBC spectroscopic data.
Databáze: MEDLINE