| Autor: |
Adams CS; Department of Chemistry, University of Wisconsin, Madison, Wisconsin 53706, USA. schomakerj@chem.wisc.edu., Weatherly CD, Burke EG, Schomaker JM |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical Society reviews [Chem Soc Rev] 2014 May 07; Vol. 43 (9), pp. 3136-63. Date of Electronic Publication: 2014 Mar 20. |
| DOI: |
10.1039/c3cs60416k |
| Abstrakt: |
This article reviews methods for converting allenes to strained, three-membered methylene heterocycles, and also covers the reactivity of these products. Specifically, the synthesis and reactivity of methylene aziridines, allene oxides/spirodiepoxides, methylene silacyclopropanes, methylene phosphiranes, and methylene thiiranes are described, including applications to the synthesis of complex molecules. Due to the primary focus on heterocyclic motifs, the all-carbon analogue of these species (methylene cyclopropane) is only briefly discussed. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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