Unusual activation of H2 by reduced cobalt complexes supported by a PNP pincer ligand.

Autor: Rozenel SS; University of California, Berkeley, 510 Latimer Hall, Berkeley, USA. arnold@berkeley.edu., Padilla R, Camp C, Arnold J
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Mar 11; Vol. 50 (20), pp. 2612-4.
DOI: 10.1039/c3cc46018e
Abstrakt: The reactivity of cobalt complexes supported by a PNP pincer ligand towards H2 varies depending on whether the N-donor atom is protonated; the synthesis of [(HPNP)CoCl(H)2] (2), [(PNP)CoH]2 (4), and the trihydride species [(HPNP)CoH3] (7) (HPNP = HN(CH2CH2P(i)Pr2)2) are described.
Databáze: MEDLINE