Three-dimensional conformal coatings through the entrapment of polymer membrane precursors.

Autor: Nguyen du T; Department of Chemistry, ‡Department of Physics and Astronomy, and §Rapid Tech, University of California , Irvine, California 92697, United States., Kleiman M, Ryu KA, Hiew S, Brubaker K, Mughnetsyan R, Truong R, Dolan B, Tackett E, Esser-Kahn AP
Jazyk: angličtina
Zdroj: ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2014 Feb 26; Vol. 6 (4), pp. 2830-5. Date of Electronic Publication: 2014 Feb 03.
DOI: 10.1021/am4053943
Abstrakt: We report a technique to coat polymers onto 3D surfaces distinct from traditional spray, spin, or dip coating. In our technique, the surface of a template structure composed of poly(lactic acid) swells and entraps a soluble polymer precursor. Once entrapped, the precursor is cured, resulting in a thin, conformal membrane. The thickness of each coating depends on the coating solution composition, residence time, and template size. Thicknesses ranged from 400 nm to 4 μm within the experimental conditions we explored. The coating method was compatible with a range of polymers. Complicated 3D structures and microstructures of 10 μm thickness and separation were coated using this technique. The templates can also be selectively removed, leaving behind a hollow membrane structure in the shape of the original printed, extruded, or microporous template structures. This technique may be useful in applications that benefit from three-dimensional membrane topologies, including catalysis, separations, and potentially tissue engineering.
Databáze: MEDLINE