Lacinilene C 7-methyl ether.

Autor: Uzbekov VV; A.S. Sadykov Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo Ulugbek str. 83, Tashkent 100125, Uzbekistan., Talipov SA; A.S. Sadykov Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo Ulugbek str. 83, Tashkent 100125, Uzbekistan., Ibragimov BT; A.S. Sadykov Institute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo Ulugbek str. 83, Tashkent 100125, Uzbekistan., Stipanovic RD; Southern Plains Agricultural Research Center, Agricultural Research Service, USDA, College Station, TX 77845, USA., Bell AA; Southern Plains Agricultural Research Center, Agricultural Research Service, USDA, College Station, TX 77845, USA.
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2013 Aug 07; Vol. 69 (Pt 9), pp. o1392. Date of Electronic Publication: 2013 Aug 07 (Print Publication: 2013).
DOI: 10.1107/S1600536813021430
Abstrakt: The title compound, C16H20O3 [systematic name: 1-hy-droxy-7-meth-oxy-1,6-dimethyl-4-(propan-2-yl)naphthalen-2(1H)-one], is a sesquiterpene isolated from foliar tissues of the cotton plant and is of inter-est with respect to its anti-bacterial properties. Its phenyl ring is ideally planar, and the maximum of deviation in the second ring is 0.386 (3) Å. The hy-droxy group and the methyl group are oriented in an equatorial fashion and axial, respectively, to the second ring. In the crystal, inversion dimers are formed through pairs of O-H⋯O hydrogen bonds. Weak C-H⋯O hydrogen bonds link the dimers into columns along the c axis. These columns form a crystal structure with a crystal packing factor of 0.66.
Databáze: MEDLINE