Counter-current acid leaching process for the removal of Cu, Pb, Sb and Zn from shooting range soil.

Autor: Lafond S; Centre Eau, Terre et Environnement, Institut National de la Recherche Scientifique, Université du Québec, Québec, Canada., Blais JF; Centre Eau, Terre et Environnement, Institut National de la Recherche Scientifique, Université du Québec, Québec, Canada., Mercier G; Centre Eau, Terre et Environnement, Institut National de la Recherche Scientifique, Université du Québec, Québec, Canada., Martel R; Centre Eau, Terre et Environnement, Institut National de la Recherche Scientifique, Université du Québec, Québec, Canada.
Jazyk: angličtina
Zdroj: Environmental technology [Environ Technol] 2013 Jul-Aug; Vol. 34 (13-16), pp. 2377-87.
DOI: 10.1080/09593330.2013.770560
Abstrakt: This research explores the performance of a counter-current leaching process (CCLP) for Cu, Pb, Sb and Zn extraction in a polluted shooting range soil. The initial metal concentrations in the soil were 1790 mg Cu/kg, 48,300 mg Pb/kg, 840 mg Sb/kg and 368 mg Zn/kg. The leaching process consisted of five one-hour acid leaching steps, which used 1 M H2SO4 + 4 M NaCl (20 degrees C, soil suspension = 100 g/L) followed by two water rinsing steps. Ten counter-current remediation cycles were completed and the average metal removal yields were 98.3 +/- 0.3% of Cu, 99.5 +/- 0.1% of Pb, 75.5 +/- 5.1% of Sb and 29.1 +/- 27.2% of Zn. The quality of metal leaching did not deteriorate throughout the 10 remediation cycles completed for this study. The CCLP reduced acid and salt use by approximately 68% and reduced water consumption by approximately 60%, exceeding reductions achieved by a standard acid leaching process.
Databáze: MEDLINE