| Autor: |
Wrixon JD; Department of Chemistry and Biochemistry, The University of Windsor, 401 Sunset Avenue, Windsor, ON N9B 3P4, Canada. jmrawson@uwindsor.ca., Hayward JJ, Raza O, Rawson JM |
| Jazyk: |
angličtina |
| Zdroj: |
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2014 Feb 07; Vol. 43 (5), pp. 2134-9. |
| DOI: |
10.1039/c3dt52802b |
| Abstrakt: |
Oxidative addition of the electron-rich tetra-methoxy-dibenzo-1,2,5,6-tetrathiocine [(MeO)2C6H2S2]2 to zero-valent group 10 transition metal complexes in the presence of diphenylphosphinoethane (dppe) affords the corresponding dithiolate complexes, [(DMOBD)M(dppe)] (DMOBD = dimethoxybenzenedithiolato, (MeO)2C6H2S2(2-); M = Ni, Pd, Pt) in high yield which were characterized by single crystal X-ray diffraction. Whereas the Pd and Pt complexes exhibit two quasi-reversible 1e(-) oxidation processes, the nickel species undergoes a quasi-reversible 1e(-) reduction. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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