Supramolecular chains of high nuclearity {Mn(III)25} barrel-like single molecule magnets.

Autor: Giannopoulos DP; Department of Chemistry, Brock University, St. Catharines, Ontario L2S 3A1, Canada. tstamatatos@brocku.ca., Thuijs A, Wernsdorfer W, Pilkington M, Christou G, Stamatatos TC
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Jan 25; Vol. 50 (7), pp. 779-81.
DOI: 10.1039/c3cc47094f
Abstrakt: The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {Mn(III)25} barrel-like cluster linked via Na(+) cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.
Databáze: MEDLINE