Structural requirements for efficient photoinduced electron transfer (PET) quenching in 9-aminoalkylanthracenes.

Autor: Beeson JC; Department of Chemistry, The Ohio State University, 43210, Columbus, Ohio., Huston ME, Pollard DA, Venkatachalam TK, Czarnik AW
Jazyk: angličtina
Zdroj: Journal of fluorescence [J Fluoresc] 1993 Jun; Vol. 3 (2), pp. 65-8.
DOI: 10.1007/BF00865319
Abstrakt: The structure-quenching relationship in 9-aminoalkylanthracenes is examined by the synthesis and fluorescence evaluation of five derivatives; it is observed that benzylic 2° and 3° amines lead to ≥95% quenching of anthracene fluorescence in water, while other amines afford substantially lower quenching efficiencies.
Databáze: MEDLINE