| Autor: |
Matveeva ED; Department of Chemistry, Moscow State Lomonosov University , Lenin Hills, 1, 119992, Moscow, Russian Federation., Podrugina TA, Taranova MA, Vinogradov DS, Gleiter R, Zefirov NS |
| Jazyk: |
angličtina |
| Zdroj: |
The Journal of organic chemistry [J Org Chem] 2013 Dec 06; Vol. 78 (23), pp. 11691-7. Date of Electronic Publication: 2013 Nov 18. |
| DOI: |
10.1021/jo401514d |
| Abstrakt: |
The preparation and chemistry of novel sulfonyl- and phosphoryl-derived λ(3)-iodanes are reported. These compounds with three different heteroatoms attached to a negatively charged C atom represent potentially useful reagents that combine in one molecule the synthetic advantages of a phosphonium ylide and an iodonium salt. Specifically, they can react with a number of acetylenes, leading to hitherto unknown sulfonyl- and phosphoryl-substituted phosphinolines, phosphininothiophenes, and a novel type of annelated P-containing heterocycle--phosphininopyrazole. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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