| Autor: |
Eshghi H; Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, P.O. Box 91775-1436, Mashhad, Iran., Seyedi SM, Zarei ER |
| Jazyk: |
angličtina |
| Zdroj: |
ISRN organic chemistry [ISRN Org Chem] 2011 Mar 29; Vol. 2011, pp. 195850. Date of Electronic Publication: 2011 Mar 29 (Print Publication: 2011). |
| DOI: |
10.5402/2011/195850 |
| Abstrakt: |
Ferric hydrogensulfate catalyzed the synthesis of 5-substituted 1H-tetrazoles via [2 + 3] cycloaddition of nitriles and sodium azide. This method has the advantages of high yields, simple methodology, and easy workup. The catalyst can be recovered by simple filtration and reused delivering good yields. Also, ferric hydrogensulfate catalyzed the hydrolysis of nitriles to primary amides under aqueous conditions. Various aliphatic and aromatic nitriles converted to the corresponding amides in good yields without any contamination with carboxylic acids. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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