Rapid and systematic access to quasi-diblock copolymer libraries covering a comprehensive composition range by sequential RAFT polymerization in an Automated synthesizer.

Autor: Haven JJ; CSIRO, Materials Science and Engineering, Bag 10, Clayton South MDC, Victoria, 3169, Australia; Department of Chemical Engineering, Eindhoven University of Technology, Den Dolech 2, Eindhoven, 5612AZ, The Netherlands., Guerrero-Sanchez C, Keddie DJ, Moad G
Jazyk: angličtina
Zdroj: Macromolecular rapid communications [Macromol Rapid Commun] 2014 Feb; Vol. 35 (4), pp. 492-7. Date of Electronic Publication: 2013 Aug 29.
DOI: 10.1002/marc.201300459
Abstrakt: A versatile, cost-effective approach to the rapid, fully unattended preparation of systematic quasi-diblock copolymer libraries via sequential RAFT polymerization in an automated synthesizer is reported. The procedure is demonstrated with the synthesis of a 23 member library of low dispersity poly(butyl methacrylate)-quasiblock-poly(methyl methacrylate) covering a wide (fivefold) range of molar mass for the second block in a one-pot, sequential, RAFT polymerization.
(© 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE
Externí odkaz: