Synthesis and properties of the 5,10,15-trimesityltruxen-5-yl radical.

Autor: Frantz DK; Department of Chemistry, Massachusetts Institute of Technology , 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States., Walish JJ, Swager TM
Jazyk: angličtina
Zdroj: Organic letters [Org Lett] 2013 Sep 20; Vol. 15 (18), pp. 4782-5. Date of Electronic Publication: 2013 Aug 27.
DOI: 10.1021/ol402153w
Abstrakt: The synthesis of a long-lived, truxene-based radical that is highly delocalized and exhibits a narrow EPR absorption is reported. The radical is stable for multiple hours in a solution exposed to air and remains for months in the solid state under inert gas. Characterization and properties are discussed.
Databáze: MEDLINE