Ionothermal synthesis of two oxalate-bridged lanthanide(III) chains with slow magnetization relaxation by using a deep eutectic solvent.

Autor: Meng Y; Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry & Chemical Engineering, Sun Yat-Sen University, 510275 Guangzhou, P. R. China. tongml@mail.sysu.edu.cn., Liu JL, Zhang ZM, Lin WQ, Lin ZJ, Tong ML
Jazyk: angličtina
Zdroj: Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2013 Sep 28; Vol. 42 (36), pp. 12853-6. Date of Electronic Publication: 2013 Aug 01.
DOI: 10.1039/c3dt51816g
Abstrakt: Two novel isostructural oxalate-bridged lanthanide(III) chains, (choline)[Ln(ox)(H2O)3Cl]Cl·H2O (Ln = Dy/Er), were first obtained ionothermally by using a choline chloride-oxalic acid eutectic mixture as both solvent and structure-directing agent, both of which show field-induced slow relaxation of magnetization.
Databáze: MEDLINE