| Autor: |
Urbina-Blanco CA; EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK., Skibiński M, O'Hagan D, Nolan SP |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Aug 21; Vol. 49 (65), pp. 7201-3. Date of Electronic Publication: 2013 Jul 11. |
| DOI: |
10.1039/c3cc44312d |
| Abstrakt: |
The gem-difluoromethylene (CF2) group significantly accelerates ring-closing metathesis of 1,8-nonadienes relative to the methylene (CH2) group demonstrating similar rate accelerations to that observed for the classic Thorpe-Ingold substituents, diester malonates and ketals. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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