| Autor: |
Cooksey JP; School of Chemistry, University of Leeds, Leeds LS2 9JT, UK. j.p.cooksey@leeds.ac.uk |
| Jazyk: |
angličtina |
| Zdroj: |
Organic & biomolecular chemistry [Org Biomol Chem] 2013 Aug 21; Vol. 11 (31), pp. 5117-26. Date of Electronic Publication: 2013 Jun 28. |
| DOI: |
10.1039/c3ob40894a |
| Abstrakt: |
A key step in the synthesis of a C1-C11 fragment of the ionophore antibiotic Zincophorin involves the addition of an α-alkoxyalkylcopper(I) reagent to a planar chiral, neutral π-allyl iron complex. The key allylic alkylation reaction is highly regio- and stereoselective with addition taking place at the γ-position anti to the metal centre. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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