Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand.

Autor: Guillet GL; Center for Catalysis, Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA., Sloane FT, Ermert DM, Calkins MW, Peprah MK, Knowles ES, Čižmár E, Abboud KA, Meisel MW, Murray LJ
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Jul 28; Vol. 49 (59), pp. 6635-7.
DOI: 10.1039/c3cc43395a
Abstrakt: A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ(3), μ, and terminal coordination modes are observed for the halide donors.
Databáze: MEDLINE