Reversible 2D/3D coatings from zipper-assembly of block copolymer micelles.
| Autor: | Tyagi P; IEM (Institut Europeen des Membranes), UMR 5635 (CNRS-ENSCM-UM2), Université Montpellier 2, Place E. Bataillon, F- 34095, Montpellier, France., Raschip IE, Deratani A, Quemener D |
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| Jazyk: | angličtina |
| Zdroj: | Advanced materials (Deerfield Beach, Fla.) [Adv Mater] 2013 Jul 19; Vol. 25 (27), pp. 3739-44. Date of Electronic Publication: 2013 Jun 10. |
| DOI: | 10.1002/adma.201300631 |
| Abstrakt: | A zipper-assembly of micelles into 2D/3D coatings is reported. Block copolymer micelles that incorporate a poly(n-octadecyl methacrylate) block are zipped and unzipped on demand onto a PMMA surface. The mechanism implies an interdigitation of molecular brushes enabling 15 nm micelles to be assembled into monolayers or multilayers. (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.) |
| Databáze: | MEDLINE |
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