Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties.

Autor: Vilela SM; Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal., Firmino AD, Mendes RF, Fernandes JA, Ananias D, Valente AA, Ott H, Carlos LD, Rocha J, Tomé JP, Paz FA
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Jul 21; Vol. 49 (57), pp. 6400-2.
DOI: 10.1039/c3cc42632g
Abstrakt: A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H4bmt)(H5bmt)(H2O)2]·3H2O coordination polymers is presented. The La(3+)-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu(3+)- and Tb(3+)-doped materials are very effective UV-to-visible light converters.
Databáze: MEDLINE