Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects.

Autor: Harding DJ; Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat 80161, Thailand. hdavid@wu.ac.th, Phonsri W, Harding P, Gass IA, Murray KS, Moubaraki B, Cashion JD, Liu L, Telfer SG
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Jul 18; Vol. 49 (56), pp. 6340-2.
DOI: 10.1039/c3cc42125b
Abstrakt: The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.
Databáze: MEDLINE