Thermoelectric properties of PbSe₀.₅Te₀.₅: x (PbI₂) with endotaxial nanostructures: a promising n-type thermoelectric material.

Autor: Rawat PK; Materials Science Centre, Indian Institute of Technology, Kharagpur 721302, India., Paul B, Banerji P
Jazyk: angličtina
Zdroj: Nanotechnology [Nanotechnology] 2013 May 31; Vol. 24 (21), pp. 215401. Date of Electronic Publication: 2013 Apr 26.
DOI: 10.1088/0957-4484/24/21/215401
Abstrakt: In the present investigation, we report on the thermoelectric properties of PbSe₀.₅Te₀.₅: x (PbI₂) from room temperature to 625 K. High-resolution transmission electron micrographs of the samples reveal endotaxial nanostructures embedded in a PbSe₀.₅Te₀.₅ matrix. The combined effect of mass fluctuation and nanostructures reduces the thermal conductivity to a great extent compared to PbTe and PbSe, without affecting the carrier mobility. As a result, a thermoelectric figure of merit with a value of 1.5 is achieved at 625 K. This value is significantly higher than that of the available state-of-the-art n-type materials.
Databáze: MEDLINE