| Autor: |
Xu X; Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA., Qian Y, Zavalij PY, Doyle MP |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2013 Jan 30; Vol. 135 (4), pp. 1244-7. Date of Electronic Publication: 2013 Jan 17. |
| DOI: |
10.1021/ja311392m |
| Abstrakt: |
Transition-metal catalysts direct 1,2-C→C, -O→C, and -N→C migrations from β-methylene-β-silyloxy-β-amido-α-diazoacetates with high selectivity. The key to achieving this unique display of differential selectivities relies on steric and stereoelectronic control by their catalytically generated metal carbenes. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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