| Autor: |
Djebli Y; Université Mentouri de Constantine, 25000 Constantine, Algeria., Boufas S, Bencharif L, Roisnel T, Bencharif M |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Nov 01; Vol. 68 (Pt 11), pp. m1411-2. Date of Electronic Publication: 2012 Oct 27. |
| DOI: |
10.1107/S1600536812041967 |
| Abstrakt: |
The title complex, [Cu(SO(4))(C(6)H(8)N(2))(2)]·H(2)O, was obtained under hydro-thermal conditions. The Cu(II) ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two benzene-1,2-diamine ligands at the base and one O atom from a monodentate sulfate anion at the apex of the coordination polyhedron. N-H⋯O hydrogen bonding between the amino functions and the sulfate groups leads to the formation of layers parallel to (001). C-H⋯O hydrogen bonding inter-actions between the layers consolidate the three-dimensional set-up. There are voids in the structure filled with lattice water mol-ecules that are disordered over three sites in a 0.430 (6):0.270 (6):0.300 (6) ratio. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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