Concise syntheses of insect pheromones using Z-selective cross metathesis.
| Autor: | Herbert MB; Department of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, 91125, USA., Marx VM, Pederson RL, Grubbs RH |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2013 Jan 02; Vol. 52 (1), pp. 310-4. Date of Electronic Publication: 2012 Oct 10. |
| DOI: | 10.1002/anie.201206079 |
| Abstrakt: | Very short synthetic routes to nine cis-olefin-containing pheromones containing a variety of functionality, including an unconjugated (E,Z) diene, are reported. These lepidopteran pheromones are used extensively for pest control, and were easily prepared using ruthenium-based Z-selective cross metathesis, highlighting the advantages of this method over less efficient ways to form Z olefins. (Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.) |
| Databáze: | MEDLINE |
| Externí odkaz: |
|
Plný text