| Autor: |
Subashini A, Ramamurthi K, Stoeckli-Evans H |
| Jazyk: |
angličtina |
| Zdroj: |
Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Sep 01; Vol. 68 (Pt 9), pp. m1152. Date of Electronic Publication: 2012 Aug 04. |
| DOI: |
10.1107/S1600536812033922 |
| Abstrakt: |
In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol-ecules are linked via pairs of N-H⋯Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N-H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
|
