Cobalt(III) complexes as functional ligands for metal (oxide) surfaces.

Autor: Cooper RJ; EaStCHEM School of Chemistry, The University of Edinburgh, EH9 3JJ, UK., Jane RT, Jeffs TE, Hartshorn RM, Tasker PA
Jazyk: angličtina
Zdroj: Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Oct 07; Vol. 48 (77), pp. 9583-5.
DOI: 10.1039/c2cc34598f
Abstrakt: Co(III) polyamine complexes with either two or three labile coordination sites bind strongly to high surface area metal oxides such as goethite or aluminium trihydroxide, and have been shown to act as passivating agents for aluminium flake in aqueous media, in addition to providing a potential method for surface functionalisation.
Databáze: MEDLINE