Bis(tetra-ethyl-ammonium) oxalate dihydrate.

Autor: McNeese TJ, Pike RD
Jazyk: angličtina
Zdroj: Acta crystallographica. Section E, Structure reports online [Acta Crystallogr Sect E Struct Rep Online] 2012 Aug 01; Vol. 68 (Pt 8), pp. o2382-3. Date of Electronic Publication: 2012 Jul 07.
DOI: 10.1107/S160053681203022X
Abstrakt: The title compound, 2C(8)H(20)N(+)·C(2)O(4) (2-)·2H(2)O, synthesized by neutralizing H(2)C(2)O(4)·2H(2)O with (C(2)H(5))(4)NOH in a 1:2 molar ratio, is a deliquescent solid. The oxalate ion is nonplanar, with a dihedral angle between carboxyl-ate groups of 64.37 (2)°. O-H⋯O hydrogen bonds of moderate strength link the O atoms of the water mol-ecules and the oxalate ions into rings parallel to the c axis. The rings exhibit the graph-set motif R(4) (4)(12). In addition, there are weak C-H⋯O inter-actions in the crystal structure.
Databáze: MEDLINE