| Autor: |
Greene MA; Department of Chemistry, New York University, New York, New York 10003, United States., Prévost M, Tolopilo J, Woerpel KA |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2012 Aug 01; Vol. 134 (30), pp. 12482-4. Date of Electronic Publication: 2012 Jul 20. |
| DOI: |
10.1021/ja305713v |
| Abstrakt: |
Silver-catalyzed silylene transfer to alkenes forms vinylsilacyclopropanes regioselectively. These allylic silanes undergo additions to aldehydes to form seven-membered-ring trans-alkenes with high diastereoselectivity. The high reactivity of the trans-alkenes is evidenced by their formal [1,3]-sigmatropic rearrangement reactions and the rapid additions of oxygen-hydrogen bonds across the carbon-carbon double bonds. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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