Optical properties of bismuth tellurite based glass.
Autor: | Oo HM; Physics Department, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia., Mohamed-Kamari H; Physics Department, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia., Wan-Yusoff WMD; Physics Department, Faculty of Science, University Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia. |
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Jazyk: | angličtina |
Zdroj: | International journal of molecular sciences [Int J Mol Sci] 2012; Vol. 13 (4), pp. 4623-4631. Date of Electronic Publication: 2012 Apr 11. |
DOI: | 10.3390/ijms13044623 |
Abstrakt: | A series of binary tellurite based glasses (Bi(2)O(3))(x) (TeO(2))(100-) (x) was prepared by melt quenching method. The density, molar volume and refractive index increase when bismuth ions Bi(3+) increase, this is due to the increased polarization of the ions Bi(3+) and the enhanced formation of non-bridging oxygen (NBO). The Fourier transform infrared spectroscopy (FTIR) results show the bonding of the glass sample and the optical band gap, E(opt) decreases while the refractive index increases when the ion Bi(3+) content increases. |
Databáze: | MEDLINE |
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