| Autor: |
Bozoklu G; Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique, CEA-Grenoble, INAC, France., Gateau C, Imbert D, Pécaut J, Robeyns K, Filinchuk Y, Memon F, Muller G, Mazzanti M |
| Jazyk: |
angličtina |
| Zdroj: |
Journal of the American Chemical Society [J Am Chem Soc] 2012 May 23; Vol. 134 (20), pp. 8372-5. Date of Electronic Publication: 2012 May 14. |
| DOI: |
10.1021/ja3020814 |
| Abstrakt: |
The chiral dissymmetric tetradentate ligand (S)-6'-(4-phenyloxazolin-2-yl)-2,2'-bipyridine-6-carboxylate (S-Phbipox) leads to the diastereoselective assembly of a homochiral Eu(3+) triangle and a highly emissive (quantum yield = 27%) heptanuclear wheel that is the largest example of a chiral luminescent complex of Eu(3+) reported to date. The nuclearity of the assembly is controlled by the solvent and the Eu(3+) cation. All of the compounds show large circularly polarized luminescence with an activity that varies with the nature of the assembly (highest for the homochiral trimer). |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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