| Autor: |
Adelani PO; Department of Civil Engineering and Geological Sciences, University of Notre Dame, Notre Dame, Indiana 46556, USA., Oliver AG, Albrecht-Schmitt TE |
| Jazyk: |
angličtina |
| Zdroj: |
Inorganic chemistry [Inorg Chem] 2012 May 07; Vol. 51 (9), pp. 4885-7. Date of Electronic Publication: 2012 Apr 20. |
| DOI: |
10.1021/ic300035n |
| Abstrakt: |
A novel uranium heteropolyoxometalate, [H(3)O](4)[Ni(H(2)O)(3)](4){Ni[(UO(2))(PO(3)C(6)H(4)CO(2))](3)(PO(4)H)}(4)·2.72H(2)O, has been prepared under mild hydrothermal conditions using the diethyl(2-ethoxycarbonylphenyl)phosphonate ligand and in situ ligand synthesis of the HPO(4)(2-) anion. The cluster is derived from a common UO(7), pentagonal bipyramid and is constructed by employing nickel(II) metal ions as linkers. The 3d-5f heteropolyoxometalate core incorporates 12 classical pentagonal uranyl groups and four Ni(2+) octahedral units. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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