Simple and versatile selective synthesis of neutral and cationic copper(I) N-heterocyclic carbene complexes using an electrochemical procedure.
| Autor: | Lake BR; School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, LS2 9JT, UK., Bullough EK, Williams TJ, Whitwood AC, Little MA, Willans CE |
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| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 May 18; Vol. 48 (40), pp. 4887-9. Date of Electronic Publication: 2012 Apr 13. |
| DOI: | 10.1039/c2cc30862b |
| Abstrakt: | An electrochemical approach for the preparation of copper(I) N-heterocyclic carbene complexes has been developed to include a diverse range of ligand precursors. Importantly, the method is effective for a ligand precursor that contains several acidic protons and for which traditional methods of carbene formation are not suitable. (This journal is © The Royal Society of Chemistry 2012) |
| Databáze: | MEDLINE |
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