Arynes and cyclohexyne in natural product synthesis.

Autor: Gampe CM; Laboratorium für Organische Chemie, ETH Zürich, Switzerland., Carreira EM
Jazyk: angličtina
Zdroj: Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2012 Apr 16; Vol. 51 (16), pp. 3766-78. Date of Electronic Publication: 2012 Mar 15.
DOI: 10.1002/anie.201107485
Abstrakt: This Minireview highlights recent advances in the field of aryne and cyclohexyne chemistry that have allowed the extraordinary reactivity of these entities to be harnessed during the course of natural product syntheses. The syntheses presented rely on the use of these reactive species in chemoselective transformations and follow unprecedented synthetic strategies that are inspiring for the practitioners of synthetic organic chemistry.
(Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Databáze: MEDLINE