| Abstrakt: |
In the title hydrated salt, C(6)H(9)N(2)O(+)·C(14)H(9)O(3) (-)·H(2)O, the dihedral angle between the benzene rings of the 2-benzoyl-benzoate anion is 82.04 (14)°, while the angles between the aromatic ring of the pyridinium cation and each of the benzene rings of the anion are 4.42 (14) and 82.04 (14)°. In the crystal, mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, generating a three-dimensional network with R(2) (2)(8), R(6) (6)(16) and R(4) (4)(6) motifs. The crystal packing is further stabilized by two π-π inter-actions, one between pyridinium rings, and another between the benzene benzoate and pyridinium rings of neighbouring mol-ecules, with centroid-to-centroid distances of 3.559 (2) and 3.606 (2) Å, respectively. |
