Ammonium release from a blanket peatland into headwater stream systems.
Autor: | Daniels SM; Upland Environments Research Unit, Geography, School of Environment and Development, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK. steve1001@mac.com, Evans MG, Agnew CT, Allott TE |
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Jazyk: | angličtina |
Zdroj: | Environmental pollution (Barking, Essex : 1987) [Environ Pollut] 2012 Apr; Vol. 163, pp. 261-72. Date of Electronic Publication: 2012 Jan 28. |
DOI: | 10.1016/j.envpol.2012.01.004 |
Abstrakt: | Hydrochemical sampling of South Pennine (UK) headwater streams draining eroded upland peatlands demonstrates these systems are nitrogen saturated, with significant leaching of dissolved inorganic nitrogen (DIN), particularly ammonium, during both stormflow and baseflow conditions. DIN leaching at sub-catchment scale is controlled by geomorphological context; in catchments with low gully densities ammonium leaching dominates whereas highly gullied catchments leach ammonium and nitrate since lower water tables and increased aeration encourages nitrification. Stormflow flux calculations indicate that: approximately equivalent amounts of nitrate are deposited and exported; ammonium export significantly exceeds atmospheric inputs. This suggests two ammonium sources: high atmospheric loadings; and mineralisation of organic nitrogen stored in peat. Downstream trends indicate rapid transformation of leached ammonium into nitrate. It is important that low-order headwater streams are adequately considered when assessing impacts of atmospheric loads on the hydrochemistry of stream networks, especially with respect to erosion, climate change and reduced precipitation. (Copyright © 2012 Elsevier Ltd. All rights reserved.) |
Databáze: | MEDLINE |
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