Mirror symmetry breaking and chiral amplification in foldamer-based supramolecular helical aggregates.
| Autor: | Azeroual S; Department of Chemistry & Biochemistry, Concordia University, 7141 Sherbrooke St. West, Montréal, Québec, Canada H4B 1R6., Surprenant J, Lazzara TD, Kocun M, Tao Y, Cuccia LA, Lehn JM |
|---|---|
| Jazyk: | angličtina |
| Zdroj: | Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2012 Feb 25; Vol. 48 (17), pp. 2292-4. Date of Electronic Publication: 2012 Jan 23. |
| DOI: | 10.1039/c2cc16266k |
| Abstrakt: | Spontaneous asymmetric generation of supramolecular chiral fibers was observed in the folding induced self-assembly of a lock-washer shaped foldamer. A secondary nucleation growth mechanism is proposed to explain the observed chiral amplification or deracemization of these supramolecular fibers. (This journal is © The Royal Society of Chemistry 2012) |
| Databáze: | MEDLINE |
| Externí odkaz: |
|