| Autor: |
Marhenke J; Department of Physical Sciences, Butte College, Oroville, California 95965, USA., Pierri AE, Lomotan M, Damon PL, Ford PC, Works C |
| Jazyk: |
angličtina |
| Zdroj: |
Inorganic chemistry [Inorg Chem] 2011 Dec 05; Vol. 50 (23), pp. 11850-2. Date of Electronic Publication: 2011 Oct 28. |
| DOI: |
10.1021/ic201523r |
| Abstrakt: |
Flash and continuous photolysis studies of (μ-pdt)[Fe(CO)(3)](2) under excess CO were conducted in coordinating and noncoordinating solvents. The back-reaction of CO with the photoproduct showed second-order kinetics with k(CO) values of 1.0 × 10(8), 3.4 × 10(6), 1.2 × 10(6), and 0.90 M(-1) s(-1) in hexanes, benzene, toluene, and THF, respectively. These data indicate a solvent-coordinated intermediate as one photoproduct, but other long-lived species were also apparent. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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