| Autor: |
Koumousi ES; Department of Chemistry, University of Patras, 26500 Patras, Greece., Mukherjee S, Beavers CM, Teat SJ, Christou G, Stamatatos TC |
| Jazyk: |
angličtina |
| Zdroj: |
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2011 Oct 21; Vol. 47 (39), pp. 11128-30. Date of Electronic Publication: 2011 Sep 09. |
| DOI: |
10.1039/c1cc13770k |
| Abstrakt: |
Synthetic access has been achieved into high oxidation state Mn/Ca chemistry with the 4 : 1 Mn : Ca stoichiometry of the oxygen-evolving complex (OEC) of plants and cyanobacteria; the anion of (Et(3)NH)(2)[Mn(III)(4)Ca(O(2)CPh)(4)(shi)(4)] has a square pyramidal metal topology and an S = 0 ground state. |
| Databáze: |
MEDLINE |
| Externí odkaz: |
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